The theory assumes that reactants are hard spheres rather than molecules with specific structures. In 1935, Henry Eyring helped develop a new theory called the transition state theory to provide a more accurate alternative to the previously used Arrhenius equation and the collision theory. The Eyring equation involves the statistical frequency.. Transition state theory relies on three key assumptions in its derivation. Reactants are in constant equilibrium with the transition state structure. The energy of the particles follow a Boltzmann distribution.. The Eyring equation can also be expressed in terms thermodynamic parameters.
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California State University East Bay. Transition state theory was proposed in 1935 by Henry Erying, and further developed by Merrideth G. Evans and Michael Polanyi (Laidler & King, 1983), as another means of accounting for chemical reaction rates. It is based on the idea that a molecular collision that leads to reaction must pass through an.. Transition-state theory allows for the characterization of kinetic processes in terms of enthalpy and entropy of activation by using the Eyring equation. However, for reactions in solution, it fails to take the change of viscosity of solvents with temperature into account.
